As promised, here a glimpse of why I believe that recombination in organic bulk heterojunction solar cells under short circuit conditions (and also at Voc) is not necessarily monomolecular.
Sometimes, the short circuit current density vs light intensity is measured, and from the linear scaling a dominant monomolecular recombination is concluded. In (partial) answer, we have performed some relevant device simulations (thanx to wapf). In short, we varied the generation of free charges over four orders of magnitude, assuming different polaron recombination mechanisms.
Continue reading “Type of Polaron Recombination under Short Circuit Conditions [Update]”
I finished the Review article I was recently talking about. If you are interested, the preprint can be accessed here
(in a few hours, 20:00 EST according to arXiv, so be patient;-) [Update 2nd March 2010] It’s up:-)
Reviews seem to be pretty subjective, and I am sure there are many omissions, but hopefully not too many inconsistencies. If there are any particular things you do like or do not like, or which are plain wrong: I am happy about every bit of constructive criticism! I submitted the article to Rep. Prog. Phys. It will be peer-reviewed, and I am pretty sure the referees’ comments will make the current version much less final as I’d like it to be;-)
[Update 25.6.2010] The review was accepted after some minor revisions, and is scheduled for publication by Rep. Prog. Phys. in September (2010).
Add to Connotea
Via pv-tech. Brief note on efficiency record: Solarmer has managed to get an (NREL certified) power conversion efficiency of 7.9% for an organic solar cell… sounds good, and broke the recent record (by the same company). It is important to mention, though, that the active area was very small with 0.1cm2 (aperture 0.047cm2).
Add to Connotea
Many people believe that organic photovoltaics companies will have to prove soon that they can come up with commercially viable products within the next two-three years. In this context, Heliatek, a Germany based company developing organic small molecule solar cells with high efficiency, has received 18 Million Euros in a second round of funding from venture capitalists and others. From the press release:
Heliatek will be utilizing the new funding primarily to build an initial production facility in Dresden. In this step and right through to mass production, the company will be using its proprietary tandem technology to efficiently produce, flexible and very lightweight PV modules on a film substrate. Their weight will be merely 500 grams per square meter, instead of today’s customary 20 kilograms per square meter. This will open up a forward-looking market for mobile applications, for architectural solutions and for independently supplying regions with weak infrastructures.
Indeed, interesting times for OPV – particularly in view of the commercial aspects! The science aspects are also getting more and more interesting, but unfortunately I thus have less and less time to write about them here…
P.S. Another company Solexant just starts the production of hybrid solar cells after the process developed by the group of Paul Alivisatos at Berkeley, as reported by Technology Review.
Add to Connotea